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CO₂ decaf

CO₂ decaffeination uses supercritical carbon dioxide to dissolve caffeine from green coffee, keeping flavor and leaving no residue. Why it is mostly industrial.

CO₂ decaffeination uses carbon dioxide held above its critical point, where it behaves as both a liquid and a gas.

How it works

Moistened green coffee is placed in a pressure vessel and supercritical CO₂ is circulated through it at very high pressure. The CO₂ selectively dissolves caffeine while leaving most larger flavor molecules behind.

The caffeine is then separated and the CO₂ recycled.

Why it works well

Selectivity. CO₂ is unusually good at targeting caffeine specifically, so flavor retention is excellent — arguably the best of the commercial methods.

No solvent residue. The CO₂ simply evaporates.

The limitation

Cost. The pressure vessels are expensive and only economic at industrial scale, which is why CO₂ decaf tends to appear in large-volume commercial coffee rather than in small specialty lots.

What to look for

Bags rarely specify. If a decaf is from a specialty roaster it is most likely Swiss Water or EA; if it is a supermarket brand it may well be CO₂ or a solvent method.

Brewing it

Grind coarser and re-dial. Decaffeinated beans are drier and more brittle than regular beans, so they grind finer at the same setting and extract faster; start a step or two coarser and adjust by taste. Decaffeinated beans are drier and more brittle than regular beans, so they grind finer at the same setting and extract faster; start a step or two coarser and adjust by taste.

What you need to make it

The equipment this actually requires — not a shopping list, the shortest route to doing it properly.